Intermolecular interaction

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Contents

Used for

van der Waals force

See for

chemical interaction, nucleotide protein interaction

Broader Terms

chemistry

Narrower Terms

chemical association, chemical binding, molecular stacking, protein protein interaction

Related Terms

chemical reaction, surface plasmon resonance

Scope Note

1946-8426

Facts (generated by robot; please edit if you find it inaccurate)

  • Problems Discussed In Class Groups in class identified the types of interactions that would occur in pure samples of the following molecules of similar molecular weights: 1-butanol: strongest intermolecular interaction is hydrogen bonding, gives relatively high boiling point (actual BP=117.
  • The third type of intermolecular interaction is the hydrogen bond and can be regarded as an extreme form of dipole-dipole interaction that occurs when hydrogen is bonded to the elements nitrogen, oxygen and fluorine.
  • Since atomic arrangements with this mutual orientation result in a smaller overlap between the flat areas of adjacent C70, the energy gain due to the intermolecular interaction is smaller than that for the orientation of θ= 0.
  • A reduced effect is noticed in the MP2 results, probably indicating that the charge-transfer contribution to the intermolecular interaction is less significant at this level.
  • The nature of the intermolecular interaction is not well understood and is still a matter of some debate; A number of theories were put forward in the 1960s, of which those proposed by McConnell have received greatest attention [2].

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