go to a health care provider/planned parenthood/family planning clinic/doctors office and ask for a consultation about the pill. they will explain everything to you, how it works and how to take it. the consultation is free and doesnt take long. its a great idea and very protective against pregnancy.
typically, you would take the first pill of your pack on the first day of your menstrual cycle. (day 1 of your period). you wont be able to have unprotected sex on the pill until you have been on it for at least a month.
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