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Rosacea is a chronic facial skin condition that affects mostly fair-skinned women between the ages of 30-60 years old. Symptoms can include areas of redness on the face, small, spidery-like collections of blood vessels on the nose or cheeks.
Chrysanthellum indicum : Chrysanthellum indicum is derived from mother's daisy (golden chamomile) flower. This herb contains phenylpropanoic acid, flavonoids, and saponoids which have been found to stabilize and strengthen the walls of blood vessels. In a recent study, chrysanthemum indicum in a topical cream showed significant improvements in how much of the face was affected and how reddened the skin was. 1
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Chibixiao- Chibixiao is a formulation derived from Traditional Chinese Medicine (TCM) principles and contains loquat leaf, mulberry bark, scutellaria root, imperata rhizome, red peony root, safflower, red sage root, chuanxiong, dahurian angelica root, motherwort, and Chinese trumpet creeper flower.  The cure rate was 87.5% and the recurrence rate was 6.5%. The control group, treated only with spironolactone, showed only a 45% cure rate with a 41.2% recurrence rate.2

Azelaic acid, used in the conventional treatment of rosacea, is a naturally occurring acid found in whole grain cereals and animal products.  Azelaic acid has been shown to tone and normalize skin cell growth and function as an antibiotic as well.  The Food and Drug Administration (FDA) has approved it as a topical preparation to treat acne, and it has shown some usefulness in treating rosacea as well.  In one trial of a cream containing 20% azelaic acid, patients with the pustule form of rosacea experienced a 73% decrease in inflammation and a 48% reduction in redness scores. There were only mild adverse reactions.3
 
Another trial compared azelaic acid with metronidazole—patients reported greater success and satisfaction with the azelaic acid treatments.4

Glycyrrhiza glabra (Licorice) has been traditionally used to treat rosacea and is generally considered as safe (GRAS) by the FDA.  A 10-20% glycyrrhiza cream has been used, most often with other herbs such as Echinacea, Pau d’arco, turmeric, rose hips, aloe, burdock, tea tree oil and chamomile. Tea tree oil can be used alone in a cream where it generally is used at 5-20%.

Vitamins that are often recommended include beta-carotenes and Vitamin A, Vitamins E and C, and the minerals zinc and selenium.

Probiotics and digestive enzymes have sometimes been recommended (along with the betaine-HCl) to aid in proper digestion and absorption of foods.  It has long been believed in naturopathic medicine that a good deal of health depends on a healthy GI system—and this is where the probiotics, the digestive enzymes and proper acid levels can help.